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To prevent global warming, further reductions in carbon dioxide are required. It is therefore important to promote the spread of electric vehicles powered by internal combustion engines and electric vehicles without internal combustion engines. As a result, emissions from hybrid electric vehicles equipped with internal combustion engines should be further reduced. Interest in catalytic reactions in an electric field with a higher catalytic activity compared to conventional catalysts has increased because this technology consumes less energy than other electrical heating devices. This study was therefore undertaken to apply a catalytic reaction in an electric field to an exhaust emission control. First, the original experimental equipment was built with a high voltage system used to conduct catalytic activity tests.

Three-way catalyst (TWC) converters are often used to purify toxic substances contained in exhaust emissions from gasoline engines. However, a large amount of CO, NOx and THC may be emitted before the TWC reaches its light-off temperature during a cold start. In this work, a numerical model was developed for studying the purification performance of a close-coupled TWC converter during the cold start period. The TWC model was built using axisuite, commercial software by Exothermia S.A. Model gas experiments were designed for calibrating the chemical reaction scheme and corresponding reaction rate parameters in the TWC model. The TWC model was able to simulate the purification performance of CO, NOx and THC under both lean and rich air-fuel equivalence ratios (λ) for different conditions. The light-off temperature and oxygen storage capacity (OSC) behavior were also successfully validated in the model. Vehicle tests were conducted on a chassis dynamometer to verify the TWC model.

Urea SCR (Selective Catalytic Reduction) exhaust after-treatment systems are one of the most promising measures to reduce NOx emissions from diesel engines. Both Cu-zeolite (Cu-SCR) and Fe-zeolite (Fe-SCR) urea SCR systems have been studied extensively but not many detailed studies have been conducted on the combination of both systems. Thus, we carried out studies on such Combined-SCR systems and their capability to reduce NOx under various engine operating conditions. We also conducted transient engine tests using different catalyst systems to compare their performance. The results show that combined-SCR systems can reduce NOx more effectively than Fe-SCR or Cu-SCR alone. The best NOx reduction performance was achieved at a Cu ratio of 0.667 (i.e. Fe: Cu =1: 2). Combined-SCR thus apparently benefits from the characteristics of both Cu-SCR and Fe-SCR, allowing it to reduce NOx over a wide range of operating conditions.

Pre-chamber (PC) natural gas and hydrogen (CH4-H2) combustion can improve thermal efficiency and greenhouse gas emissions from decarbonized stationary engines. However, the engine efficiency is worsened by prolonged combustion duration due to PC jet velocity extinction. This work investigates the impact of cylindrical PC internal shapes to increase its jet velocity and shorten combustion duration. A rapid compression and expansion machine (RCEM) is used to investigate the combustion characteristics of premixed CH4 gas. The combustion images are recorded using a high-speed camera of 10,000 fps. The experiments are conducted using two types of long PC shapes with diameters φ=4 mm (hereafter, longφ4) and 5 mm (hereafter, long φ5), and their combustions are compared against a short PC shape (φ=12 mm). For all designs of the PC shapes, the PC holes are 6 with 2 mm in diameter.

Synthetic fuels can significantly improve the combustion and emission characteristics of heavy-duty diesel engines toward decarbonizing heavy-duty propulsion systems. This work analyzes the effects of engine operating conditions and synthetic fuel properties on spray, combustion, and emissions (soot, NOx) using a supercharging single-cylinder engine experiment and KIVA-4 code combined with CHEMKIN-II and in-house phenomenological soot model. The blended fuel ratio is fixed at 80% diesel and 20% n-paraffin by volume (hereafter DP). Diesel, DP1 (diesel with n-pentane C5H12), DP2 (diesel with n-hexane C6H14), and DP3 (diesel with n-heptane C7H16) are used in engine-like-condition constant volume chamber (CVC) and engine experiments. Boosted engine experiments (1080 rpm, common-rail injection pressure 160 MPa, multi-pulse injection) are performed using the same DP fuel groups under various main injection timings, pulse-injection intervals, and EGR = 0-40%.

To identify ways of achieving good mixture formation and heat release in diesel spray combustion, we have performed Large Eddy Simulation (LES) using a detailed chemical reaction mechanism to study the temporal and spatial distribution of the local equivalence ratios and heat release rate. Here we characterize the effect of the fuel injection rate profile on these processes in the combustion chamber of a diesel engine. Two injection rate profiles are considered: a standard (STD) profile, which is a typical modern common rail injection profile, and the inverse delta (IVD) profile, which has the potential to suppress rich mixture formation in the spray tip region. Experimental data indicate that the formation of such mixtures may extend the duration of the late combustion period and thus reduce thermal efficiency.

We have proposed a new compressive combustion principle leading to the auto-ignition of fuel by focusing compression due to the collision of the pulsed supermulti-jets. This principle has the potential of nearly-complete air insulation due to encasing burned gas around the center of the combustion chamber and a high compression ratio around the chamber center while suppressing vibration and noise levels. We have developed the first prototype engine having a very small combustion chamber of a diameter of 18 mm and also 14 side passages for the supermulti-jets colliding at the chamber center. Combustion experimental results indicating air insulation effect and high thrust over 100 N were obtained as basic data for various types of applications, including automobiles and aerospace usage such as for rockets. However, it was found that higher compression due to more jets is necessary to get stabler combustion.

In a Diesel Oxidation Catalyst (DOC) and Catalyzed Soot Filter (CSF) system, the DOC is used to oxidize additional fuel injected into the cylinder and/or exhaust pipe in order to increase the CSF's inlet temperature during soot regeneration. The catalyst's hydrocarbon (HC) oxidation performance is known to be strongly affected by the HC species present and the catalyst design. However, the engine operating conditions and additive fuel supply parameters also affect the oxidation performance of DOCs, but the effects of these variables have been insufficiently examined. Therefore, in this study, the oxidation performance of a DOC was examined in experiments in which both exhaust gas recirculation (EGR) levels and exhaust pipe injection parameters were varied. The results were then analyzed and optimal conditions were identified using modeFRONTIER.

In our previous reports, we proposed a new focusing engine with high thermal efficiency based on relatively-silent high compression and nearly-complete air-insulation effect, which employs pulsed multi-jets of gas collided around chamber center. Local compression level due to the gas jets colliding around chamber center before reaction can be varied from zero to 100MPa and 3000K, by changing the number of jets and intake pressure. Relatively-silent high compression is possible, because region around chamber wall is at pressure level of traditional engines. This is suitable for various usages of automobiles, aerocrafts, and rockets, and also for various fuels including hydrogen, because high compression around chamber center leads to stable auto-ignition and potential of low NOx at very lean burning operation. We developed two types of focusing compression engines, without and with piston. For the new engine without piston, we obtained nearly-complete air-insulation and high thrust.